The skull is of medium length, broad between the ears. The forehead line is moderately arched as seen from the side. The occipital bone well developed without being conspicuous. The stop is well defined.
The Rottweiler nose is well developed, more broad than round with relatively large nostrils and always black. The muzzle should appear neither elongated nor shortened in relation to the cranial region. The nasal bridge is broad at the base and moderately tapered.
The lips are black and close fitting with the corner of the mouth not visible. The gums should be as dark as possible.
Both the upper and lower jaws are strong and broad. According to the FCI Standard Rottweilers should have strong and complete dentition (42 teeth) with scissor bite, the upper incisors closely overlapping the lower incisors.
The zygomatic arches should be pronounced. The eyes should be of medium size, almond-shaped and dark brown in colour. The eyelids are close fitting.
The ears are medium-sized, pendant, triangular, wide apart, and set on high. With the ears laid forward close to the head, the skull appears to be broadened.
The skin on the head is tight fitting overall. When the dog is alert, the forehead may be slightly wrinkled.